Polydispersity and EXAFS simulations
نویسندگان
چکیده
منابع مشابه
The influence of polydispersity and inhomogeneity on EXAFS of bimetallic catalysts
The effect of polydispersity and inhomogeneity of supported bimetallic catalysts on the EXAFS analysis is investigated with some simple model calculations. These show that EXAFS is very insensitive to polydispersity. Polydispersity and inhomogeneous distribution of the metals over the particles however have only limited influence on the ability to distinguish between core-shell particles and pa...
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In real systems, inelastic processes remove photoelectrons from the elastic scattering channel. This reduces the amplitude of the EXAFS causing disagreement between the experimental and theoretically predicted amplitudes. Traditionally these discrepancies were treated by including two semi empirical reduction factors in the data analysis: a mean tree path term, which models the so called extrin...
متن کاملParticle Survival and Polydispersity in Aggregation
– We study the probability, PS(t), of a cluster to remain intact in one-dimensional cluster-cluster aggregation when the cluster diffusion coefficient scales with size as D(s) ∼ s . PS(t) exhibits a stretched exponential decay for γ < 0 and the power-laws t −3/2 for γ = 0, and t for 0 < γ < 2. A random walk picture explains the discontinuous and non-monotonic behavior of the exponent. The decay...
متن کاملPolymolecularity and Polydispersity in Molecular Weight Determinations
The influence of polymolecularity on molecular weight determinations is reviewed. Several molecular weight methods give so-called mixed averages, i.e. averages which are based on more than one moment of the molecular weight distribution or on powers of the moment. Molecular weight averages can be subdivided into simple, exponential resolved, order resolved and power resolved averages. Mixed ave...
متن کاملOverview of the standard EXAFS data analysis procedure Introduction Interpretation of EXAFS data is normally based on the EXAFS equation
with appropriate accomodation for forward scattering (\focussing e ect") for higher shells, and inclusion of higher cumulants as necessary. The aim of data analysis is to determine the distances, coordination numbers, disorder parameters and types of atoms in the various coordination shells for the \unknown" sample. The extent to which this is possible depends on the nature of the system, the q...
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ژورنال
عنوان ژورنال: Journal of Physics: Conference Series
سال: 2009
ISSN: 1742-6596
DOI: 10.1088/1742-6596/190/1/012027